化學肥料從生產到施用的每一步,都隱藏驚人的能源消耗與碳排放,氨合成更佔全球能源的2%、碳排放更勝航運與航空總和。若不改變施肥方式,農田將成為氣候危機的沉默推手。
化學肥料生產與施用之碳排放與能源消耗概述
化學肥料在現代農業生產中扮演著至關重要的角色,為作物提供必需的養分,以維持並提高糧食產量。這些肥料主要包含氮、磷、鉀等巨量元素,以及其他微量元素,對於確保全球糧食安全做出了巨大貢獻 1。然而,化學肥料的生產、運輸和施用過程,同時也對環境造成顯著影響,尤其是在碳排放和能源消耗方面。本報告旨在深入分析化學肥料從原料開採到最終施用於農田的整個生命週期中所涉及的碳排放與能源消耗,從而全面評估其環境足跡。
報告將涵蓋化學肥料生命週期的各個關鍵階段,包括原料的開採與處理、不同種類化學肥料(如氮肥、磷肥和鉀肥)的製造過程、肥料的運輸與配送,以及最終在農田中的施用。透過對每個階段的能源投入和溫室氣體排放進行詳細分析,本報告旨在揭示化學肥料生產和使用在全球溫室氣體排放和能源消耗中的重要性。研究指出,肥料產業的碳排放量在全球溫室氣體排放中佔據相當比例,甚至超過了全球航空和航運的總排放量 2。因此,深入理解化學肥料的生命週期碳排放,對於制定有效的減排策略至關重要。
化學肥料的製造過程與能源消耗
化學肥料的製造是一個複雜且能源密集的過程,不同種類的肥料由於其化學組成和生產工藝的差異,在能源消耗方面也存在顯著的區別。
氮肥
- 氨合成 (Haber-Bosch 製程) 氨是生產大多數氮肥的核心中間體,其合成主要依賴於 Haber-Bosch 製程。該製程涉及在高溫(400-500°C)和高壓(150-300 bar)條件下,使用鐵基催化劑將大氣中的氮氣與氫氣反應生成氨 4。氫氣的主要來源通常是天然氣,透過蒸汽甲烷重整等方式獲得 4。天然氣不僅作為氫氣的原料,也是提供製程所需熱能的主要來源,佔氨生產成本的 70-90% 4。高溫高壓的反應條件是 Haber-Bosch 製程能源消耗巨大的主要原因 4。催化劑的應用雖然降低了反應的活化能,但仍無法完全消除對高能量輸入的需求 6。現代化的氨生產廠平均每生產一噸氮需要消耗約 29.7 百萬 BTU 的能量 7,遠高於理論最低能耗 5。氨合成的能源消耗約佔全球總能源消耗的 2% 4。
- 其他氮肥生產 氨作為中間體,可進一步加工生產尿素、硝酸銨等多種其他氮肥 7。將氨升級為這些最終產品需要額外的能源投入。例如,生產一噸尿素需要約 35.9 百萬 BTU 的能量,而生產尿素硝酸銨溶液則需要約 31.4 百萬 BTU 的能量 7。這些能源消耗量高於最初的氨合成過程,顯示了氮肥生產鏈中顯著的能源投資。
- 磷肥 磷肥的生產始於磷酸鹽礦的開採與處理 22。開採後的磷酸鹽礦經過一系列的破碎、篩選和濃縮等物理處理,以提高磷的含量。隨後,磷酸鹽礦主要通過濕法工藝生產磷酸,這是製造大多數磷肥(如磷酸二銨和過磷酸鈣)的關鍵步驟 22。濕法工藝相較於熱法工藝,由於其較低的能源需求而更為常用 25。磷肥的能源消耗估計約為每磅五氧化二磷 5,600 BTU 27,雖然低於氮肥,但由於其龐大的生產量,仍然是農業部門能源消耗的重要組成部分。
- 鉀肥 鉀肥的生產主要涉及鉀礦的開採與處理 28。鉀礦通常以氯化鉀(KCl)和硫酸鉀(K2SO4)等形式存在。開採方法包括傳統的地下開採和溶液開採,其中溶液開採通常需要更多的能源用於蒸汽產生和泵送 33。鉀肥的能源消耗估計約為每磅氧化鉀 4,700 BTU 27,是三種主要大量元素肥料中最低的。加拿大作為主要的鉀肥生產國,其鉀肥生產的溫室氣體排放強度低於全球平均水平 35。
化學肥料製造過程的碳排放
化學肥料的生產過程不僅消耗大量能源,同時也產生顯著的碳排放,對氣候變遷構成威脅。
- 氨合成的直接與間接碳排放 氨合成是化學肥料生產中碳排放的主要來源之一。該過程直接排放二氧化碳作為副產品 5,同時,由於大量依賴天然氣和電力等化石能源,也產生了顯著的間接碳排放 5。據估計,氨合成在全球二氧化碳排放量中佔比約為 1-2%,與全球航空業的排放量相當 4。因此,實現氨生產過程的脫碳對於降低肥料的碳足跡至關重要。
- 其他化學肥料生產的碳排放 其他化學肥料的生產也涉及碳排放。尿素和硝酸銨等氮肥的生產,雖然以氨為原料,但其轉化過程同樣會產生碳排放。磷肥的生產,估計每噸排放約 1.7 噸二氧化碳當量 43,而鉀肥的碳排放量相對較低,約為每噸 0.6 噸二氧化碳當量 43。生產技術和能源結構的選擇對這些排放水平有顯著影響。
化學肥料的運輸與能源消耗
化學肥料從生產工廠到農田的運輸過程也消耗能源並產生碳排放。
- 從生產工廠到農田的運輸方式 化學肥料通常透過火車、卡車和輪船等多種方式從生產工廠運輸到農田。運輸方式的選擇取決於運輸距離、肥料的數量和地理位置等因素。
運輸過程的能源消耗與碳排放 不同運輸方式的能源效率存在顯著差異 28。火車和輪船通常在長距離運輸方面更具能源效率,而卡車則更適用於短距離的配送。運輸距離的長短直接影響總體的能源消耗和碳排放量 28。儘管如此,肥料運輸僅佔合成氮肥總生命週期排放量的一小部分,估計約為 2.6% 48。
農田施用化學肥料的能源消耗
化學肥料在農田的施用也需要消耗能源。
- 農業機械的使用 施肥過程主要依賴農業機械,如拖拉機和施肥機等。這些機械通常以柴油為燃料。
- 施肥過程的能源需求 不同的施肥方法,如撒施、條施和葉面噴施,其能源效率可能有所不同。精準農業技術的發展,例如變量施肥技術,有潛力根據作物的實際需求精確施用肥料,從而減少不必要的能源消耗 47。
化學肥料的生命週期評估
生命週期評估(LCA)提供了一個全面的框架,用於評估化學肥料從原料開採到最終施用的整個過程中的環境影響。
- 從原料開採到最終施用的整體碳足跡 LCA 研究顯示,氮肥由於其高能源需求的生產過程和在農田中釋放的強效溫室氣體一氧化二氮,通常具有最高的碳足跡。磷肥和鉀肥的碳足跡相對較低。總體而言,化學肥料生命週期中碳排放的主要熱點通常在於生產階段和使用階段。
- 不同種類化學肥料的生命週期評估數據 不同種類的氮肥、磷肥和鉀肥在 LCA 中表現出不同的碳足跡 50。這些差異主要歸因於其生產過程的能源強度和溫室氣體排放特性。
不同種類化學肥料的典型施用量與能源消耗、碳排放量化
不同種類化學肥料的典型施用量因作物種類、土壤條件和養分需求而異 49。基於這些施用量數據,結合前述的能源消耗和碳排放因子,可以量化不同化學肥料在實際應用情境中的能源消耗和碳排放。例如,尿素的典型施用量會影響其總體的能源消耗和一氧化二氮排放量。
結論與建議
本報告分析了化學肥料從製造到施用的全生命週期碳排放與能源消耗。主要發現包括氨合成的高能源強度和碳排放,以及氮肥在農田中釋放的一氧化二氮對全球暖化的潛在影響。
為減少化學肥料的碳足跡和能源消耗,建議採取以下措施:
- 提高生產效率和採用低碳生產技術:開發和推廣更節能的氨合成技術,並採用可再生能源作為生產過程的能源來源 2。
- 優化肥料使用,減少過量施用:根據土壤測試和作物需求精確施用肥料,避免過量使用,從而減少能源浪費和溫室氣體排放 2。
- 推廣緩釋肥料和硝化抑制劑的使用:緩釋肥料可以更有效地將養分釋放給作物,減少養分流失和一氧化二氮排放。硝化抑制劑可以減緩土壤中硝化作用的速度,從而減少一氧化二氮的產生 [2, S_S139, S_S154, S_S172, S_S232, S_S315, S_S317, S_S322, 207, 210, 216, 2。
- 改善肥料運輸和儲存效率:優化運輸路線和方式,減少運輸過程中的能源消耗和損耗。
- 推動農業中的精準施肥技術:利用遙感、地理資訊系統等技術,實現肥料的精確施用,提高養分利用率,減少能源消耗和環境影響 [47, 49。
- 鼓勵使用有機肥料和綠肥作為補充或替代方案:有機肥料和綠肥的生產過程通常比化學肥料更節能,且有助於改善土壤健康 59。
政策制定者應制定相關法規和激勵措施,鼓勵採用更可持續的肥料生產和管理方法。農業生產者應積極採納精準施肥技術和最佳管理實踐,提高肥料利用效率,減少對環境的影響。研究人員應持續探索和開發低碳肥料生產技術和更有效的施肥策略,以應對氣候變遷和糧食安全挑戰。
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